Methylformate from CO2: an integrated process combining catalytic hydrogenation and reactive distillation
نویسندگان
چکیده
منابع مشابه
Hydricity of an Fe-H Species and Catalytic CO2 Hydrogenation.
Despite renewed interest in carbon dioxide (CO2) reduction chemistry, examples of homogeneous iron catalysts that hydrogenate CO2 are limited compared to their noble-metal counterparts. Knowledge of the thermodynamic properties of iron hydride complexes, including M-H hydricities (ΔGH(-)), could aid in the development of new iron-based catalysts. Here we present the experimentally determined hy...
متن کاملCatalytic CO2 Hydrogenation - Literature Review: Technology Development since 2014
Global atmospheric carbon dioxide (CO2) concentration from fossil fuel combustion has generated much concern because of the several environmental issues associated with high levels of atmospheric CO2, a major greenhouse gas. In order to reduce the risks associated with global warming, the increase in atmospheric CO2 concentration must be prevented. CO2 capture and conversion not only mitigates ...
متن کاملCombining Conceptual and Detailed Methods for Batch Distillation Process Design
The separation of multicomponent mixtures by batch distillation generally requires the sequential processing of several splits in one column. The sequencing of the splits and the choice of the column configuration, e.g. regular or inverse column, has a substantial impact on the economic potential of the process. Beside these structural design decisions the profitability of the process is furthe...
متن کاملReactive Distillation: Control Structure and Process Design for Robustness
Reactive Distillation (RD) is the combination of reaction and distillation in a single vessel (Backhaus, 1921). Over the past two decades, it has emerged as a promising alternative to conventional “reaction followed by separation” processes (Towler & Frey, 2002). The technology is attractive when the reactant-product component relative volatilities allow recycle of reactants into the reactive z...
متن کاملan integrated process monitoring approach combining dynamic independent component analysis and local outlier factor
in this paper a novel process monitoring scheme for reducing the type і and type іі error rates in the monitoring phase is proposed. first, the proposed approach uses an augmented data matrix to implement the process dynamic. then, we apply independent component analysis (ica) transformation to the augmented data matrix, and eliminate the outliers using the local outlier factor (lof) algorithm....
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Green Chemistry
سال: 2019
ISSN: 1463-9262,1463-9270
DOI: 10.1039/c9gc03006a